Wednesday, January 29, 2014

Periodic table d block ans

1 ueka.ksia $lafrdaushus $jefkavshus hk fusjdfha NdIausl Ulaihsv i|yka lrkak
VO / V2O3
MnO
Mn2O3
2 wdus,sl Tlaihsv f,i yeisfrkafka ljrlao@
Mn2O7
MnO3
CrO
CrO2
CrO3
V2O5
3 WNh.=ks ixfhda. jkafka ljrla o@
MnO2
VO2
Cr2O3


4 +1 TlaislrK wjia:dj olakg fkdue;af;a ljr uQ, o%jH j, o@
Sc / Zn
5 +2 TlaislrK wjia:dj olakg fkdue;af;a ljr uQ, o%jH j, o@
Sc
6 +3 TlaislrK wjia:dj olakg fkdue;af;a ljr uQ, o%jH j, o@
Zn
7 +4 TlaislrK wjia:dj olakg fkdue;af;a ljr uQ, o%jH j, o@
Sc / Zn / Cu
8 +5 TlaislrK wjia:dj olakg we;af;a ljr uQ, o%jH j, o@
V / Mn / Cr / Fe / Co
9 +6 TlaislrK wjia:dj olakg fkdue;af;a ljr uQ, o%jH j, o@
Mn / Cr / Fe
10 +7 TlaislrK wjia:dj olakg we;af;a ljr uQ, o%jHhg o@
Mn




Tn okakd d f.dkqfjs whk fyda oS we;s ,jK w;rska iudk j¾K iys; ,jK f;darkak
1 [Cu (NH3)4] +2 2 - [Ni (NH3) 6] +2 3 - Co (NH3) 6] +2 4 - Cr(NH3) 6] +2
5 Ni (H2O) 6] +2 6 - Cu (H2O) 6] +2 7 - Cr(H2O) 4] +2 8 - Fe (H2O) 6] +3 9 - Co (H2O) 6] +2
10 – CuCl4 11 Cr(H2O) 5Cl 12 - NiCl2 13 Ni (OH) 2 14 – CoCl4
15 V O2+ 16 VO22+ 7 - V 3+ 18 -- V 2+
19 - Mn(H2O) 6] +2 20 - Cr(H2O) 6] +2 21. Cr(H2O) 6] +3 22 Ni(NH3) 6] +3


ks,a j¾Kh --- 6 $1 $3 $14 $2 $15 $20
fld< j¾Kh --- 11 $7 $13 $17 $ Fe +2 (aq) / Ni +2 (aq)
ly j¾Kh --- 8 $4 $12 $10 $16 $3
ous j¾Kh --- 18 $ Cr +3 (aq) / Ti+3 (aq) / Mn+3 (aq)/ 21
frdai j¾Kh ---9 $19
oqUqre -- 22 $
ksrslaIK j,g .e,fmk ,jKh bosrsm;a lrkak
1 ks,a ous meye;s c,Sh o%djKhla fidavshus yhsfv%dlaihsvs H2O2 fhoQjsg lymdg o%djKhla ,nd fohs
ks,a ous meye;s o%djKh Cr +3
2 laf,darhsvhlg idkao% HCl fhoQ jsg lymdg o%djKhla ,efnhs ,efnk o%djKh fldm¾
f,dayh iu. kegjQ jsg wj¾K jQ w;r thg c,h fhosfusoS R iqoq wjlafIamhla ,enqKs
Cu+2
lymdg o%djKh CuCl4 -2
wj¾K jQ o%djKh 2[ CuCl2 ]-2
iqoq wjlafIamhla CuCl
3 R iqoq wjlafIamh wefudakshus yhsfv%dlaihsvs tl;= l< jsg oshjS idok wj¾K o%djKh
jd;hg jsjD; l< jsg ;oks,a meyehg yefrhs
wj¾K o%djKh [Cu (NH3)2] +
;oks,a meyeh 2[Cu (NH3)4] +2


4 ks,a meye;s c,sh o%djKhlg jevsmqr NaOH fhoQjsg ,d ks,a meye whlafIamhla ,efnhs th r;a l< jsg l,q wjlafIamhla ,enqKs


ks,a meye;s c,sh o%djKh -- [Cu (H2O) 6] +2
,d ks,a meye whlafIamhla --- [Cu( OH) 2(H2O) 4]
l,q wjlafIamhla CuO
5 ks,a meye;s c,sh o%djKhlg wefudakshd tl;=l< jsg ,efnk wjlafIamh jevsmqr wefudakshd tl; =l< jsg ,efnk ,d ks,a meye wjlafIamhla oshfjhs
,efnk o%djKfha meyeh l=ula o@
m%Yshka ks,a– [Cu( NH3 ) 4(H2O) 4]+2
Cu (NH3)4] +2


6 wefudakshus yhsfv%dlaihsvs tl;= l< jsg le; $ls,qgq fld< meye;s wjlafIamhla ,ensu tu wjlafIamh l=ula o@
fmria yhsfv%dlaihsvs $ Fe (H2O) 6] +2

7 B kus ,d ly meye;s c,Sh o%djKhla oqn, f,i NdIausl l< jsg ly oqUqre meyehla we;s jsh
Fe (H2O) 6] +3
[Fe (OH) 3 (H2O) 4]
9 B kus o%djKh id HCl u.ska wdus,sl l< jsg ,efnk ly meyeh KCN iu. oQUqre meye jsh
B kus ly oQUqre o%djKh fmdgEishus fmrsihkhsvs iu. ks,a j¾Khla fohs
oQUqre o%djKh meye h - [ Fe(CN)6] -3
10 tu ly oQUqre o%djKh KSCN /NH4SCN iu. ljr j¾Khla fohs o@
f,a r;= j¾Kh
[Fe (SCN) (H2O) 5 ] +2
11 f,dayhla ;kql HCl u.ska wdus,sl l< jsg ,efnk C kus o%djKh fld< meyehla ,nd oqks
fld< meyehla - Fe (H2O) 6] +2
12 ,d fld, meyeh gsl fjs,djlska ly oqUqre meye jSug fya;= jk ridhksl ls%hdj,sh iuSSlrKhlska fokak
Fe (H2O) 6] +2 + 4H+ + O2 = 4[Fe (H2O) 6] +3 + 2H2O
13 thg iy ;kql wus,hla yd iskala l=vq oud gsl fjs,djla ;enQ jsg l=ula isoq fjhs o@
fld< meyehla ,nd oqks
fld< meyeh - 2 Fe (H2O) 6] +2
14 fuhg NaOH fhoQ jsg we;sjk j¾Kh ,shkak
ls,qgq fld< meye;s wjlafIamhla
[Fe (OH) 2 (H2O) 4]
15 KCN iu. fmria whk ,nd fok meyeh l=ula o@
ly fld< j¾Kh
[ Fe(CN)6] -4
16 idkao% HCl iu. fmria whk ,nd fok meyeh l=ula o@
ly
[ Fe(Cl)4] -2


17 B kus ly oQUqre o%djKh fmdgEishus fmrsihkhsvs iu. m%Yshka ks,a j¾Khla fohs
oQUqre o%djKh meye h - Fe+3
18 u ly oQUqre o%djKh KSCN /NH4SCN iu. ljr j¾Khla fohs o@
f,a r;= j¾Kh
[Fe (SCN) (H2O) 5 ] +2
19 Q kus ,d frdai meye;s o%djKhlg ;kql HNO3 tl;= l< jsg ous meyehla we;s jsh NdIausl l< jsg th fld< meyehg yereKs
frdai meye;s o%djKh -- [Mn (H2O) 6] +2
ous meyeh - MnO4-1
fld< meyehg -- MnO4-2
20 Q kus ,d frdai meye;s o%djKhlg NdIausl l< jsg ly iqoq wjlafIamhla we;s jsh
th gsl fjs,djlska H2O2 we;s jsg oqUqre meyehg yereks
ly iqoq wjlafIamh Mn(OH)2 (H2O) 4] +2
oqUqre meyeh MnO2




21 fld< meye;s c kus c,Sh o%djKhla oqn, f,i wdus,sl lr gsl fjs,djla ;nd fmrd .;a jsg fmryka lvodisfha l,q meyehla o fmfrkfha ous meyehla we;s jsh iuslrKhla u.ska th ksrEmkh lrkak
3MnO4-2 +4 H+ = 2 MnO4-1 + MnO2 + 2H2O
fld< meyeh ous meyeh -


22 B kus ks,a ous meyehla we;s c,Sh ,jKhla laIdr iu. ,efnk fld< meye wjlafIamh meh lsysmhlg miq fld, meye o%djKhla ,enqKs
ous meyeh --- Cr(H2O) 6] +3
fld< meye wjlafIamh------- Cr(OH) 3 (H2O)3]
ld, meye o%djKh----- Cr(OH) 6+3
23 gsl fjs,djla ;enq jsg ous meye jkafka wehs@
idudkH WIaK;ajfha oS fiuska jsfhdackh jk ksid
24 tu o%djKh mej;s ;;ajhg fk taug l=ula l< hq;= o@
wus,hla Ndjs; l< hq;=h
25 wefudakshd o%djKh fhoQ jsg ks,a-ous o%djKh ous meyehg yereKs
ous meyehg ----Cr(NH3) 6] +3
26 ly meye;s o%djKhla wdus,sl l< jsg ;eUs,s meye;s o%djKhla ,enqKs tu o%djKhg NIauhla tl;= l, jsg isoq jkafka l=ula o@
ly meye;s o%djKh---- CrO4-2
;eUs,s meye;s o%djKh --- Cr2O7-2
ly meye;s o%djKhla ,enSu
27 f,dayhla iu. ;kql HCl u.ska wdus,sl l< jsg ,efnk ks,a meye o%djKh jd;h yuqfjs
ous meyehg yereKs
ks,a meye o%djKh ---- Cr(H2O) 6] +2
ous meyeh o%djKh ---- Cr(H2O) 6] +3
28 by; ous meyeh o%djKh kej; ly meye;s iajdNdjhg m;a lsrSug l=ula l< hq;= o@
laIdr we;s jsg H2O2 iu. ls%hdj
Cr+3 whk Cr+2 yrjkafka flfia o@
iskala ixri fhdod .ekSfuka






29 S ,d fld< meye;s o%djKhla ;kql NaOH tl;= l< jsg ,d fld< meye wjlafIamhla we;s jsh
,d fld< meye wjlafIamh [Ni(OH) 2 (H2O) 4
,d fld< meye;s s o%djKh -- [Ni (H2O) 6] +2


30 S fld< meye o%djKhla jevsmqr wefudakshd iu. idok A ,d fld < wj;afIamh oshjS ks,a ouS meye;s o%djKhla fohs th kegjQ jsg
,dfld < wj;afIamh [Ni(OH) 2 (H2O)4]
ks,a ouS meye;s o%djKh [Ni(NH3) 6] +2


31 S ,d fld< meye;s o%djKh t;fkda,a udOHfha oS ks,a meye;s o%djKhla fohs
[Ni Cl 4] -2
32 ihkhsvs whk we;sjsg ,d fld< wjlafIamhla we;sjS jevsmqr we;s jsg th oshjS ly meye;s o%djKhla fohs
,d fld< wjlafIamh -- Ni (CN)2
ly meye;s o%djKh -- [Ni (CN) 4] -2




33 laIdrSh vhs fu;s,a .a,fhdlaihsus iu. r;= wjlafIamhla fokafka ljrla o@
Ni+2
34 iqoq meye;s Tlaihsvhla iskala yd wus, udOHhloS ous meye;s o%djKhla ,nd oqks
iqoq meye;s Tlaihsvh TiO2
ous meye;s o%djKhla Ti(H2O) 6] +3
35 iqoq meye;s Tlaihsvhla idkao% HCl wus, udOHhloS wj¾K o%jKhla we;s lf<ah th r;a l< jsg iqoq wjfYaIhla b;srs jsh
[TiCl 6] -2
TiCl2


36 ;eUs,s meye Tlaihsvhla iskala yd wus, udOHhloS fld< meye;s jsh
gsl fjs,djls th ous meye;s jsh
;eUs,s meye Tlaihsvh V2O5
fld< meye;s o%djKhla V(H2O) 6] +3
ous meye;s o%djKhla V(H2O) 6] +2




37 ous meye;s o%djKhla SO2 iu. ;o ks,a meyehla ,nd oqks th wus, f,day iu.
ous meye;s o%djKhla fohs
ks,a meyehla VO2
ous meye;s o%djKhla V(H2O) 6] +2
38 ks,a meye o%djKh laIdrhla iu. l==ula ,nd fohs o@
VO 3 -2


39 P kus ,d frdai meye;s o%djKhlg ;kql NaOH tl;= l< jsg ks,a meyehla we;s jsh
jevsmqr NaOH tl;= l< jsg frdai meye T wjlafIamhla we;s jsh
P frdai meye;s o%djKh -- [Co (H2O) 6] +2
frdai meye wjlafIamh -- [Co (OH) 2 (H2O) 4]
ks,a meye wjlafIamh -- [Co (OH) (H2O) 5] +
ks,a meye wjlafIamh --- [Co (OH) 2 (H2O) 4]


40 T wj;afIamh HCl j, oshjS ks,a meye;s o%djKhla fohs
[Co Cl 4] -2
41 P wefudakshd iu. idok ks,a wj;afIamh jevsmqr wefudakshd oshjS A ly oqUqre meye;s o%djKhla fohs th kegjQ jsg
ks,a meye wjlafIamh [Co (OH) (H2O) 5] +
ly oqUqre meye;s o%djKh [Co (NH3) 6] +2




l¿ wajlafIamh [Co (OH) 3 (H2O) 3]
42 A kus o%djKhlg jd;h fyda H2O2 fhoQ jsg ;eUs,s oQUqre o%djKhla ,nd fohs
;eUs,s oQUqre o%djKh 2 [Co (NH3) 6] +3
43 whvhsvs whk njg I2 yrjkafka l=uk fldfnda,ags whkh o@
Co+3

44 wefudakshus yhsfv%dlaihsvs tl;= l< jsg oqUqre meye;s wjlafIamhla ,ensu tu wjlafIamh l=ula o@
fmrsla yhsfv%dlaihsvs
45 fmdgEishus fmfrdaihkhsvs K4Fe (CN)6 iu. iqoq wjlafIamhla ,enSu
fmriaa ,jK


46 fmdgEishus fmfrdaihkhsvs K4Fe (CN)6 iu. wjlafIamhla fkd,enSu oqUqre meyehla ,enSu


fmrsla ,jK
FeCl3 + K4Fe (CN)6 = KFe [Fe (CN)6] +3 KCl


47 fmdgEishus fmfrdaihkhsvs K4Fe (CN)6 iu. oqUqre wjlafIamhla ,enSu
2CuSO4 + K4Fe (CN)6 = Cu2Fe (CN)6] + K2SO4




48 fmdgEishus fmrsaihkhsvs K3Fe (CN)6 iu. ;o ks,amdg m%Yshka ks,amdg wjlafIamhla ,enSu
fmriaa ,jK


FeSO4 + K3Fe (CN)6 = KFe [Fe (CN)6] + K2SO4
49 fmdgEishus fmrsaihkhsvs K3Fe (CN)6 iu. wjlafIamhla fkd,enSu oqUqre meyehla ,enSu
fmrsla ,jK
fmdgEishus m¾ueka.fkags







1 comment:

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