Sunday, July 31, 2011

Electro Chemistry 1

 bf,lafg%dav jsNjh  1
iskala f,dayh  yd fldm¾ f,dayh fjk fjku lkQl wus, o%djKhla ;=, .s,ajd we;ehs is;kak
  
1  tysoS Tn n,dfmdfrd;a;= fjkiajSus ,sshkak
iskala f,dayh  f,dayh oshjSfus fjs.h  fldm¾ f,dayhg jvd  jevsfjs $wvqfjs
iskala f,dayh  jdhq nqnq¿ msgjSfus fjs.h fldm¾ f,dayhg jvd  jevsfjs $wvqfjs

2 f,dayh oshjkafka wehs@
iuSlrKhla  u.ska ksrEmkh lrkak tysoS isoqjkafka TlaislrKhla o $ TlaisyrKhla o

3 TlaislrK fjs.h jevsjSu flfia ksrslaIKh l< yels o@
 f,dayh oshjSfus fjs.h jevsjSu u.ska

4 jdhqjla f,i msgjkafka l=ula o@ tysoS isoqjkafka TlaislrKhla o $ TlaisyrKhla o
yhsv%cka
TlaisyrKhla

5 TlaisyrKh i|yd bf,lafg%dak imhd .kafka ljr mDIaGhla u.ska o@
f,day mDIaGh u; bf,lafg%dak ysÕ;djhla we;s jqjfyd;a th flfia ksrSlaIKh l< yels o@
yhsv%cka
 jdhqjla f,i msgjsfus fjs.h wvq fjhs

6 jvd;a TlaislrKh jSfus yelshdj we;af;a ljr f,dayhg o@
iskala
nslrhla ;=,g wus,h fhdod iskala f,dayh  yd fldm¾ f,dayh lkQl wus, o%djKhla ;=, .s,ajd we;ehs is;kak
 jdhqjla f,i msgjSfus  yhsv%cka msgjSfus fjs.h  iskala j,g idfmalaIj fldm¾ mDIaGfha wvq njla mej;=ks
f,day mgs tlsfkl iam¾Y l< jsg   fldm¾ mDIaGfhka yhsv%cka msgjSfus
fjs.h  fldm¾ mDIaGfha jevs jsh

7 fldm¾ mDIaGfha isoqjQ fuu fjkig fya;=j ,shkak
tu mDIaGfhka ,nd .; yels bf,lafg%dak m%udKh jevsjSu
bf,lafg%dak tlsfkl w;r jsl¾IK n, we;sfjhs  tfukau jevs bf,lafg%dak mSvkhl isg wvq bf,lafg%dak mSvkhla olajd bf,lafg%dak .uka lrhs

8 jevs jYfhka bf,lafg%dak tla reia jkafka ljr mDIaGfha o@
iskala f,dayh  u;

9 bf,lafg%dak mSvkh y|Qkajkafkaa l=ula f,ig o@
jsNjh

10 bf,lafg%dak .,d hdu ljr foilg isoqfjhs o@
iskala f,dayh  issg fldm¾ f,dayh olajd

11 Odrdj  .,d hdu ljr foilg isoqfjhs o@
fldm¾ f,dayh  issg iskala f,dayh olajd
iskala f,dayh fjkqjg ue.akSishus Ndjs; l< jsg ljr fjkia lus we;sfjhs o@

12 jevs jYfhka bf,lafg%dak tla reia jkafka ljr mDIaGfha o@
ue.akSishus f,dayh  u;

13 bf,lafg%dak .,d hdu ljr foilg isoqfjhs o@
ue.akSishu s f,dayh  issg fldm¾ f,dayh olajd


14 Odrdj  .,d hdu ljr foilg isoqfjhs o@
fldm¾ f,dayh  issg ue.akSishus f,dayh olajd

15 bf,lafg%dak mSvk  fjki ljr WmlrKhla u.ska uek .; yels o@
jsNj udkh

16 bf,lafg%dak mSvk fjki jevs w.hla .kafka l=uk f,day hq.,fha o@
 Mg  yd Cu hq.,fha

17 wus,fha idkao%Kh jevs l< jsg f,dayh TlaislrK fjs.hg l=ula isoqfjhs o@ tjsg jsNjudkfha w.h jevsfjs o@ wvqfjs o@
f,dayh TlaislrK fjs.hg jevsfjs
jevsfjs
18 fus wkqj bf,lafg%dak mSvk  fjki ljr idOl u; r|d mj;S o@
Ndjs;hg .kakd f,day hq.,h u;
jsoHq;a jspsfPofha idkao%Kh u;




Electro Chemistry 2 ans

kshus; jsIhh tall fldgi lshjSfuka wk;=rej wod, chemistans.blogspot.com  m%Yak j,g ms<s;=re imhkak'iuyr jsIhh tall fldgia  ms<sn| oekqu icSjSlrK iu. animescience.webatu.com fj;ska ,nd  .ekSug W;aidy lrkak  Tnf.a ms<s;=re iemhSu wjYH m%Yak m;%h i|yd fj; chemistans.blogspot.com  msjsfikak'                                                                            fuh Tng iajhx we.hsula jkafkah' ms<s;=re fuysoSS mrSlaId lrkak
ksrka;rfhka isoq lrk iajhx we.hSu  Wiia fm< jsNd. j,g id¾:l f,i uqyqK oSug w;aje,la jkq we;'

bf,lafg%dav iu;=,s;;dj 2

;kQl i,amshqrsla wus,h l=vd nSlr follg fjk fjku f.k A yd   B jYfhla f,an,a lrkq ,efns
 A Ndckhg   Zn f,dayh;a B Ndckhg   Cu f,dayh;a fhdod ,jK fia;=jla u.ska o%djK w;r iusnkaO;dj mj;ajd f.k we;
1 TlaislrK yelshdj jevs f,dayh f;darkak
Zn f,dayh

2 l=uk f,dayh u; bf,lafg%dak mSvkh jevs fjhso@
th fjkia l< yels fjk;a l%uhla ,shkak
 wus, idkao%Kh fjkia lsrSfuka
w.% w;r bf,lafg%dak mSvk fjki Ndjs;hg .kakd f,day hq.auh u;o r|d mj;S
tnejska hus f,dayhl TlaislrK yelshdj jsNjh u.ska uek .; yelsh

3 ljr idOl fuysoS iusu; lr .; hq;= o@
wus,fha iajNdjh
wus,fha idkao%Kh
f,day hq.auh
WIaK;ajh

4 iusu; WIaK;ajh f,i ;nd .kakd w.h lSho@
298K

5 iusu;  f,i Ndjs;hg .kakd bf,lafg%davh flfia ms<sfh, l, hq;= o@
lsishus f,dayhla ,Sgrhg fu!, 1la jk tys whk o%djKhl .s,ajd ;enSu

6 iusu; iskala bf,lafg%davh iuSmfha isoqjk m%;sls%hd ,shkak
Zn(s)            Zn++ (aq) +2e
Zn++ (aq) +2e                 Zn(s)

7 fuu m%;sls%hdj iu;=,s;;djhg m;a jQ jsg o%djKh;a bf,lafg%davh;a w;r yg.kakd jsNjh ljr kulska y|qkajhs o@
ksrfmalaI bf,lafg%dav jsNjh

8 m%dfhda.slj uekSu myiq jkafka fjk;a bf,lafg%davhlg ^ iusu; bf,lafg%davhla & idfmalaIj fuu bf,lafg%davh u; yg .kakd mSvkhhs th y|qkajk ku l=ula o@
idfmalaI bf,lafg%dav jsNjhhs

9 iusu; bf,lafg%davhla f.k thg idfmalaIj jsNjh ueksu i|yd Ndjs;hg .kafka l=ula o@
jsNjudkh

10 by; i|yka l< jsNjh m%dfhda.slj  uek.; yels o@
fkdyelsh

11 iusu; bf,lafg%davhla f,i fhdod .kafka  ljrla o@
yhsv%cka bf,lafg%davh

12 th ilid .ekSfusoS fhdod .;a bf,lafg%davh ,shkak
        Pt
 13 jsoHq;a jspsfPoHh ilid we;af;a flfia o@
,Sgrhg fu!, 1la jk tys  H+ whk o%djKhl .s,ajd  jdhq f.da, 1 l mSvkfhka yhsv%cka jdhqj hejSu

14 iusu; bf,lafg%davhl  jsNj w.h lSh o@ 
Y=kHhs

15 tu bf,lafg%davh u; isoqjsh yels m%;sls%hd ,shkak
  2H+ (aq) +2e                H2(g)
    H2(g)                         2H+ (aq) +2e

16 iusu; iskala bf,lafg%davh TlaislrKh fjhs kus  fuu iusu;  yhsv%cka bf,lafg%davhg iusnkaO l<fyd;a by; ljr m%;sls%hdj isoq fjhs o@
2H+ (aq) +2e                  H2(g)

17 ,jK fia;=j fhdokafka wehs@
  ,jK o%djK w;r ikakdhl;dj we;s lsrsug

18 iusu; f,i  iskala bf,lafg%davhla ksrEmkh lrkafka flfia o@
 Zn(s) / Zn++ (aq,1.0mol l-1)

19  iusu; f,i  yhsv%cka bf,lafg%davhla ksrEmkh lrkafka flfia o@
 H3O+ (aq,1.0 mol dm-3) / H2(g,1 atm)  ,Pt(s)           
20 ta wkqj iusu; fldaIh ksrEmkh lrkak
   Zn(s) / Zn++ (aq,1.0mol l-1)   /  H3O+ (aq,1.0 mol dm-3) / H2(g,1 atm)  ,Pt(s)           

21 tys ol=Kq miska Tn ;ensug n,dfmdfrd;a;= jkafka ljr bf,lafg%davh o@
TlaisyrK bf,lafg%davh

22 tys jus mi Tn ;ensug n,dfmdfrd;a;= jkafka ljr bf,lafg%davh o@
TlaislrK bf,lafg%davh

23 .e,ajfkduSgrfha  iQpsfha N%uKh jdudj¾;o@ olaIsKdj¾; o@
      jdudj¾; $ iDK w.hla f,i fmkajhs
24  C, iskala yd fldm¾ bf,lafg%dav i|yd ,enqKq w.hhka ms<sfj,ska  fuys olajd we;
  -  0.76V  ,            +0.34 V    ,     C      -1.18V
TlaislrK  yelsshdj by< uq, o%jHh f;dard ,shkak th wjfrdayK ms<sfj,g ilikak
C, iskala yd fldm¾

25 jvd jsoHq;a Ok uQ, o%jHh l=ula o@
C

26 jevs jsNjhla iys; fldaIhla idod .; yelafla ljr  f,day hq.,fhka o@idod .kakd fldaIfha
js' .d' n'fidhd .;yels iuSlrKhla ,shkak
C yd fldm¾
E cell    =    E RHS   E LHS          fyda             E cell     = E TlaisyrK –E TlaislrK 
         =+  0.34 V   - (-1.18V)

27 iskala yd fldm¾ iusu; ;;aj hgf;a Ndjs; l<fyd;a iEfok fldaIfha TlaislrK w¾O m%;sls%hd ,shkak  fldaI m%;sls%hdj ,shkak
TlaislrK w¾O m%;sls%hd
Zn(s)            Zn++ (aq) +2e
TlaisyrK w¾O m%;sls%hd
Cu++ (aq) +2e                Cu(s)
fldaI m%;sls%hdj
Zn(s) / Zn++ (aq,1.0mol dm-3)   /         Cu++ (aq,1.0 mol dm-3) / Cu(s)
Zn(s)    + Cu++ (aq)                                 Zn++ (aq)            +Cu(s)   H= -213KJ mol-1

28 fuu iuSlrKhg wkqj m%;sls%hdj isoqjk jsg  fldaIfha WIaK;ajh jevsfjs o@ $wvqfjs o@
fldaIfha WIaK;ajh jevsfjs

29 fuu moaO;shg iskala whk tl;= l< jsg iu;=,s;;dj ljr foig fhduq fjhs o@
iskala ;ekam;a jSu
jug fhduqjsu

30 iskala ;ekam;a jSu isoq jqjfyd;a ta i|yd jehjkafka fudkjd o@ tjsg jsNjhg l=ula isoqfjhs o@
bf,lafg%dak
bf,lafg%dak mSvkh wvqfjhs jsNjh wvqfjhs

31 fuu moaO;shg iskala whk wvq l< jsNjhg l=ula isoq fjhs o@
iu;=,s;;dj ol=Kg fhduqjsu f,dayh oshfjhs
bf,lafg%dak mSvkh jevsfjhs  bf,lafg%dav jsNjh jevs fjhs

32fuu moaO;shg fldm¾ whk jevs l< jsNjhg l=ula isoq fjhs o@
 fldm¾ f,dayh iEoSug keUqre jSu bf,lafg%davh u;  mSvkh wvqfjhs  bf,lafg%dav jsNjh jevs fjhs










Wednesday, July 27, 2011

Benzene Ans




fnkaiSka
1 fnkaiSka i|yd fll=f,a jHqyh bosrsm;a lrkak



2 fuu jHqyh fmkajk my; i|yka .=K ,shd olajkak@

w' fn%dauSka oshr iu. ---- fiuska m%;sl%shd lsrSu$ oajs wdfoaYs; M, 3la ,enSu

wd' fmdgEishus m¾uex.fkags iu. ----- m%;sl%shd fkdlsrSu

we' yhsv%cka jdhqj ksl,a f,dayh iu. r;a lsrsu ------

yhsv%ckSlrK ;dmh 3 « 119 KJ w.hg jvd wvqjSu

tla tla ksrSlaIK u.ska ,nd .; yels ks.uk ,shkak
w' fn%dauSka oshr iu. l%shdj wkqj ---oajs;aj nkaOk we;s nj
wd' fmdgEishus m¾uex.fkags iu. l%shdj wkqj----
oajs;aj nkaOk we,alSk j,g wiudk nj
we' yhsv%cka jdhqj ksl,a f,dayh iu. r;a lsrsu ------
oajs;aj nkaOk we,alSk j,g wiudk nj

fnkaiSka j, nkaOk os. w.hka i|yka lrkak
1 . 39 Ax


tu ks.uk j,g wkqj fnkaiSka j, fll=f,a jHqyh ljr fjkiajsulg Ndckh jQfha o@
oajs;aj nkaOkh ia:sr f,i ia:dk.;jS ke;s nj





3 fnkaiSka j, jHqySh ,laIK ,shkak
;,Sh wKqjla jSu
;,hg by,ska yd my,ska fvdakgs yev bf,lafg%dak j,djla mej;Su

4 fnkaiSka j, jHqySh ,laIK j,g wod,j ljr j¾.fha ridhksl m%;sl%shd fmkajhs o@
bf,lafg%dams,sl wdfoaY m%;sls%hd

5 X kus jQ ldKavhla fnkaiSka j,hg iusnkaO jqjfyd;a ta u.ska l%shdldrs;ajfha ljr fjkila we;s fjshehs un is;kafka o@

fnkaiSka j,g jvd iEfok wKqj il%sh jSu fyda jsl%sh jSu

6 thg fya;= fudkjdo@
wdfoaYjk ldKavh fnkaiSka j,fha bf,lafg%dak
idkao%Kh fnkaiSka j,g jvd jevss lsrsu fyda wvq lsrsu'

7 ta u.ska we;s lrk fjk;a n,mEula ,shkak'
fojkqj wdfoaYjk ldKavh fnkaiSka j,fha ljr ia:dkhlg wdfoaY jkafkao hkak ;SrKh lsrSu

8 fnkaiska wKqjg fojkqj wdfoaYjk ldKavh f;dard .kakd ia:dkh wkqj wdfoaYl ldKav j¾. lrhs'
tajd kus lrkak'
Tsf;d wdfoaYl $ fugd wdfoaYl $ merd wdfoaYl


9 tjeks wdfoaYl i|yd WodyrK ,shkak'
Tsf;d wdfoaYl $ merd wdfoaYl

-NH2 / -OH / -N -CH3 / - CH3 / - C6H5
-OCH3 / -NHCOCH3

fugd wdfoaYl
- COOH / - NO2

10 m%n, il%shl yd oqn, ils%hl w;r mj;sk fjki l+ula o@
wdfoaYjk ldKavh fnkaiSka j,fha bf,lafg%dak
idkao%Kh fnkaiSka j,g jvd jevss lrhs kus th m%n, il%shl f,i kus lsrsu'



-NH2 / -OH / -N -CH3 / - CH3 / - C6H5
-OCH3 / -NHCOCH3

11 by; wdfoaYl j,ska m%n, il%shl lsysmhl kus ,shkak'


-NH2 / -OH / -N -CH3

by; wdfoaYl j,ska oq¾j, il%shl lsysmhl kus ,shkak'

- CH3 / - C6H5

12 fnkaiSka j,h jsl%sh jk wjia:djla i|yka lrkak'
  • COOH / - NO2 / - Cl

13 thg fya;= fudkjdo@
wdfoaYjk ldKavh fnkaiSka j,fha bf,lafg%dak
idkao%Kh fnkaiSka j,g jvd wvq lrhs

14 fnkaiSka u.ska C6H5NO2 wjYH jk m%;sl%shl fudkjd o@
idkao% HNO3 /idkao% H2SO4 1:3


15 NO2+ ldKavfha N-O w;r mj;sk nkaOk fudkjd o@
oajs;aj nkaOk

16 NO2+ ldKavh myr fok ia:dkfha iajNdjh ,shkak'
bf,lafg%dak idkao%Kh jevs ia:dkhlg

17 fnkaiSka u.ska C6H5CH3 ksmojSug wjYH jk m%;sl%shl fudkjd o@
ks¾c,Sh AlCl3 yd CH3Cl

18 fnkaiSka u.ska C6H12 ,nd .kafka flfia o@
ksl,a f,dayh we;sjsg H2 iu. l%shdj $ r;a lsrSu

Alkyle Halide



we,alhs,a fya,hsv Wod - CH3 CH2 Cl
1 we,alhs,a fya,hsv olajk m%;sls%hd fudkjd o@
bj;ajSfus m%;sls%hd

2 tys ye,ckh bj;a jSfus yelshdj r|d mj;skafka ljr idOlhla u;o@
ye,ckfha jsoHq;a iDK;djh u;
ye,ckh iys; ldnka mrudKqfjs jsoHq;a Ok;djh u;

3 ye,ckh iys; ldnka mrudKqfjs jsoHq;a OkNdjh thg iusnkaO we,alhs,a ldKav .Kk u; flfia fjkia fjhs o@
we,alhs,a ldKav .Kk jevs jk jsg jsoHq;a Ok;djh wvqfjhs'

4 jsoHq;a Ok;djh wvqjk jsg ye,ckhg l=ula isoqfjhs o@
bj;ajSfus m%;sls%hd
A - - (CH3)3 C Cl C – C6H5 CH2 CH2 Cl B--- (CH3)2C H Cl

5 fuu ixfhda. j, ye,ckh bj;ajSfus m%;sls%hd fjs.h wvqjk ms<sfj,g olajkak'
A ,C ,B

6 m%dfhda.sl f,i jsoHd.drfhaoS th ksrSlaIKh lrkafka flfia o@
tla tla o%djKh fjk fjku f.k uOHidr iy is,aj¾ khsfgs%gs nsxoq lsysmhla fhosu'
ye,ckh bj;ajSfus m%;sls%hd fjs.h jevs kus wvq ld,hlska iqoq wjlafIamhla ,efnhs'

7 tfia bj;ajk jsg tu ia:dkhg meusfka hehs wfmalaId lrk ldKav lsysmhla ,shkak'tys mj;sk ,laIKhla ,shkak '
- OH , - CN ,
jvd jsoHq;a iDK jSu

8 tjeks ldKavhla y|qkajk ku l=ula o@
kshqla,sfhdams,sl wdfoaY m%;sls%hd

9 wefudakshd iu. isoqlrk m%;sls%hdfjs hdka;%Kh fokak'


A - - (CH3)3 C Cl C – C6H5 CH2 CH2 Cl B--- (CH3)2C H Cl D – C6H5 Cl

10 jvd ia:dhS C - Cl nkaOkh yuq jkafka ljr ixfhda.fha o@
C6H5 Cl


11 thg fya;= ,shkak
tys nkaOk os. wvqjSu $ iusm%hqla; jHqy jevs.Kkla mej;Su ksid we;sjk ia:dhS;dj

12 jskdvs 5 ld,hla ;+, ldur WIaK;ajfhaaoS myiqfjka bj;a jsh yels ye,ck mrudKq orkafka ljrla o@

A yd B
13 tu bj;a jSfus yelshdj r|d mj;sk idOl fudkjd o@

C-Cl ldnka mrudKqfjs jsoHq;a Ok nj wvqjSu u;
ye,ck mrudKqfjs jsoHq;a iDk nj jevsjSu u;

14 C-Cl ldnka mrudKqfjs jsoHq;a Ok nj jevsjSug fya;=jk idOl ,shkak'

C-Cl ldnka mrudKqjg iusnkaO we,alhs,a ldKav .Kk wkqj fyda iusnkaO jS we;s bf,lafg%dak wdl¾Il ldKav ksid


15 C6H5 CH2 CN hk wKqj idod .kafka flfia o@
C6H5 CH2 Cl iu. KCN fyda HCN m%;sls%hd lsrSu

16 .%Skdvs m%;sldrlh idod .kafka flfia o@
we,alhs,a fya,hsv iu. jsh<s B;r yd ue.akSishus l=vq iu. ls%hd lrjSu

E C6H5 CH2 CH Cl2                F C6H5 CH2 CH 2Cl
17 by; ixfhda. w;=rska we,alSk fyda we,a lhsk ,nd.; yelafla flfia o@ wjYH ;;aj fokak'
,efnk M, i|yka lrkak'
C6H5 C = CH                  C6H5 CH=CH 2

Tuesday, July 26, 2011

Equilibrium 3

iu;=,s;;dj 2 b;srs


iudk j¾K ;Sj%;dj we;s khsg%ckavfhdlaihsvs k, 3 la we;ehs is;kak  my; ;;aj hgf;a tys ksrSlaIK ,shkak

tla k,hla whsia j, ;ensu       
tla k,hla WK qc,fha ;ensu    
tla k,hla ldur WIaK;ajfha ;ensu                                                        
1 jevsu khsg%ckavfhdlaihsvs m%udKhla we;af;a l=uk k,fha o@
thg fya;= ,shkak
WK qc,fha ;enQ k,h
moaO;shg ;dmh ,nd oSfus n,mEu bj;a l< yels foig m%;sls%hdj fhduq jSu ksid $ ;dm wjfYdaIK m%;sls%hdj isoq jSu ksid bosrs w;g  m%;sls%hdj isoq jSu


2 ljr k,hl wj¾K jSu isoqfjhso@ tq u.ska .; yels ks.ukh l=ula o@
whsia j, ;enQ k,fha iEoS we;s nj
N2OiEoS we;s nj $ miq  w;g  m%;sls%hdj isoq jSu $;dm odhl m%;sls%hdj isoq jSu

3 fuu moaO;sh iu;=,s;;djhg meusK we;s nj y|qkd .kafka flfia o@
k,fha   oqUqre j¾K;Sj%;dj fjkia fkdjSu 
NO2 ,  N2O4 idkao%Kh ld,h;a iu. fjkia fkdjSu
      
4 fuu moaO;sh iu;=,s;;djh fjkia l, yels fjk;a l%uhla ,shkak
mSvkh fjkia lsrSu

5 th m%dfhda.slj isoq lrkafka flfia o@
  isrskachlg NO2 jdhqj msrjSu    
  msiagkh msg;g weosfuka  mSvkh wvq lsrSu
  msiagkh ;,a,q lsrSsfuka  mSvkh jevs  lsrSu  

6 iu;=,s;;dj fjkia lsrSu flfia y|qkd .; yels o@
msiagkh ;,a,q lsrSsfusoSa  oqUqre j¾K;Sj%;dj wvq jSu  
 msiagkh msg;g weosfuoS oqUqre j¾K;Sj%;dj jevs jSu   

7 tu WIaK;ajfhaoSu jsjsO m%usK j,ska NO2  mqrjd isrskachka jsjsO mSvk hgf;a ;enQ jsg ksh; w.hla ,nd .; yelafla idkao%Khkaf.a  ljr wkqmd;hka o@

                 [NO2]2 /  [N2O4]


8 ,efnk w.h fjkia l< yelafla flfia o@
   WIaK;ajh fjkia lsrSfuka

9   moaO;shla  ridhksl iu;=,s;;djfha  mej;Sug kus ljr lreKq iusmQ¾K jsh hq;=o@ lreKq 5 la fokak
m%;sj¾;H nj
ixjD; jSu
WIaK;ajh ksh; jSu
m%;sl%shl yd M, idkao%K ksh; jSu
mSvkh ksh; jSu