Thursday, June 6, 2013

Aldehyde and Ketones ans

CH3 - C =O
CH3







C6H5 COC2H5 / CH3 CHO / C6H5COC6H5 / CH3 COCH3 / HCHO / C6H5 CHO

1 iEu ixfhda.hlgu fmdoq ldKavh l+ula o@ th y|qkajk kduh ,shkak'
C=O ldnkhs,a ldKavh
2 tys mj;sk ldnka mrudKqj ljr j¾.fha m%;sls%hd fmkajhs o@
kshqla,sfhdams,sl wdl,k
TlaislrK m%;sls%hd
ix>kk m%;sls%hd

1 C6H5 COC2H5
2 C2H5 CHO
3 CH3 CO C2H5
4 HCHO

3 KMnO4 iu. TlaislrK m%;sls%hd olajkafka ljr ixfhda. o@
C2H5 CHO / HCHO
4 iEfok M,j, jHqy ,shkak

C2H5 COO H / HCOO H

5 fuu ixfhda. w;rska fma,sx o%djKh iu. m%;sls%hd lrkafka ljr ixfhda. o@
C2H5 CHO / HCHO
6 iefok M,fha j¾Kh ,shkak
;eUs,s j¾Kh

7 M,hla f,i wus, ,efnkafka ljr ixfhda. j,ska o@
C2H5 CHO / HCHO

8 ;kQl NaOH iu. wxl 4 flfia m%;sls%hd lrhs o@ idok M,hka ,shkak
HCOONa yd CH3OH

9 idkao% NaOH iu. wxl 2 m%;sls%hd lr idok M,h l=ula o@
frisk

10 fn%vs m%;sldrlh iu. fuu ixfhda. ,nd fok ksrSlaIKh ,shkak
;eUs,s meye wjlafIamhla idohs



11 CH3Mg Br iu. idok M,hka ,shkak

12 fgd,ka m%;sldrlh mss<sfh, lrkafka flfia o@
is,aj¾ khsfg%sgs o%djKhlg NaOH nsxoqjla fhoSu iEfok oqUqre wjlafIamh osh jk ;+re wefudakshd o%djKh tl;= lsrsu

13 fgd,ka m%;sldrlh fhdod .ksuska y|qkd .; yelafla ljr ixfhda. o@ ,efnk ksrslaIKh ,shkak
CH3 CHO / HCHO / C6H5 CHO
rsoS legm;la ,enSu


1 ldnkhs,a ixfhda. j,g ljr ixfhda. wh;a fjhs o@
we,avsyhsv
lSfgdak
2 ldnkhs,a ixfhda. j, ls%hdldrs;ajhg fya;= jkafka ldnkhs,a ldnka mrudKqfjs we;sjk O%ejsh;djhs
ljr ldKav fuu ldnka mrudKqj fj; wdl¾IKh fjhs o@
kshqla,sfhdams,sl
3 tjeks kshqla,sfhda ms,sl idok m%;sldrl y|qkajkak
HCN
CH3MgBr
CH3 NH2

4 TlaislrK yelshdj jvd;a we;af;a l=uk ixfhda. j,g o@
we,avsyhsv
5 th ;yjqre l< yels mrslaIKhla ,shkak
fma,sx o%djKh iu. .fvd,a r;= meye wjlafIamhla ,nd oSu
wefudakSh is,aj¾ khsfg%sgs iu. c, ;dmlhl r;a lsrSfus oS rsoS legm;la ,nd osu
wdus,sl KMnO4 iu.  ls%hdj $wj¾K lsrsu
6 t;ke,a yd fnkaie,avsyhsvs  w;frka jevs TlaislrK yelshdj jvd;a we;af;a l=uk ixfhda.hg o@
t;ke,a
7 ldnkhs,a ixfhda. wfkl=;a ixfhda. j,ska fjkalr y|qkd .ekSug fhdod.; yels mrslaIKhla ,shkak
fn%svs m%;sldrlh iu. olajk m%;sls%hdfjka ;eUs,s meye wjlafIamhla ,enSu
8 ldnkhs,a ixfhda. j, ls%hdldrs;ajhg fya;= jkafka ldnkhs,a ldnka mrudKqfjs we;sjk O%ejsh;djhhs  thg iusnkaO  CH3 ldkavhg we;slrk n,mEu l=ula  o@
 tys we;s C – H nkaOkh oqn, f,i O%ejslrKhg ,la lsrSu ksid  H +f,i bj;a lsrsu $ wdus,sl lsrSu isoq lrhs
we,amd yhsv%cka bj;ajs hdu
9 ljr ;;aj hgf;a fuh isoqfjhs o@
10% NaOH we;sjsg
10  we,a*d yhsv%cka bj;a jSfuka iEfok wekdhkh ljr kulska y|qkajhs o@
ldnekdhkh
11 kshqla,sfhdams,slhla f,i wdl,kh iEfok M,h myiqfjka jsc,khg Ndckh jkafka ljr ;;aj hgf;a o@
wdus,sl ;;aj hgf;a r;a l< jsg

12 tysos isoqjk m%;sls%hdfjs m<uq mshjr ;=, isoqjkafka l=ula o@
ldnekdhkh  kshqla,sfhdams,slhla f,i wdl,kh jsu
13 tysos isoqjk m%;sls%hdfjs fojk mshjr ;=, isoqjssh yelafla l=ula o@
wus,hla iu.  r;a l< jsg isoqjk jsc,kh


14 we,avsyhsv yd lsfgdak TlaisyrKhg Ndjs; lrkafka fudkjd o@ iEfok M, ,shkak
 jsh<s B;¾ we;sjsg LiAlH4 fyda NaBH4 iu. we,afldfyd, fohs

iskala ixri yd id'HCl   iu. we,aflak fohs





Alcohol ans -1

uOHidr Wod - CH3 CH2 OH



1 uOHidr olajk m%;sls%hd fudkjd o@
bj;ajSfus m%;sls%hd
TlaislrK m%;sl%shd

2 tys we;s - OH ldKavh bj;a jSfus yelshdj r|d mj;skafka ljr idOlhla u;o@

- OH iys; ldnka mrudKqfjs jsoHq;a Ok;djh u;

3 - OH iys; ldnka mrudKqfjs jsoHq;a OkNdjh thg iusnkaO we,alhs,a ldKav .Kk u; flfia fjkia fjhs o@
we,alhs,a ldKav .Kk jevs jk jsg jsoHq;a Ok;djh wvqfjhs'

4 jsoHq;a Ok;djh wvqjk jsg -OH ldKavhg l=ula isoqfjhs o@
-OH ldKavh bj;ajSfus m%;sls%hd fjs.h jevsfjhs'


5 fuu ixfhda. j, ye,ckh bj;ajSfus m%;sls%hd fjs.h wvqjk ms<sfj,g olajkak' A ,C ,B

6 m%dfhda.sl f,i jsoHd.drfhaoS th ksrSlaIKh lrkafka flfia o@
tla tla o%djKh fjk fjku f.k idkao% HCl nsxoq lsysmhla fhosu'jskdvs lsysmhla ;enSu
ye,ckh bj;ajSfus m%;sls%hd fjs.h jevs kus wvq ld,hlska wdjs,;djla ^f;,a jekas wo5djH M,hla & ,efnhs'

7 tfia bj;ajk jsg tu ia:dkhg meusfka hehs wfmalaId lrk ldKav lsysmhla ,shkak'tys mj;sk ,laIKhla ,shkak '
- Cl - Br


8 tjeks ldKavhla y|qkajk ku l=ula o@
kshqla,sfhdams,sl wdfoaY m%;sls%hd
A ,B ,C hk ixfhda.

9 idkao% HCl iu. isoqlrk m%;sls%hdfjs hdka;%Kh fokak'


10 wdus,sl KMnO4 yd wdus,sl K2Cr2O7 iu. ,efnk M, ,shkak' ,efnk ksrSlaIK fudkjd o@
ous meyeh jsj¾K jSu $oqTqre wjlafIamhla ,enSu



11 f,dayuh fidavshus iu. idokafka ljr M,hkao@
H2 yd


13 TlaislrKh isoqjk wjia:d olajkak'
f,dayuh fidavshus iu.
wdus,sl KMnO4 yd wdus,sl K2Cr2O7 iu.

14 tiagr idokafka ljrla iu. o@ wjYH m%;sl%shl ,shkak'
ldfndlais,sla wus, yd id' H2SO4

15 fuys my; i|yka tiagr iEoSug wjYH lrk m%;sls%hl j, kus ,shkak
1 C6H5COO C2H5 2 (CH3)2 CH COO C6H5
lsishus tiagrhla c,jspsfPokh l< jsg iqoq meye;s wjlafIamhla ,enqKs ' ta i|yd wjYH m%;sls%hl ,shkak'
iEfok tla M,hl ku i|yka lrkak'


16 uOHidrhlska we,alhs,a fya,hsv iEoSu i|yd Ndjs; l< fkdyels m%;sl%shl f;darkak
1 r;= P jsc, uOHidr yd Br2 2 PBr3 3 msrsvSka we;s jsg SOCl2 4. Cl2 yd NaOH
4 CH3MgBr 5. ZnCl2 yd HCl iu. m%;sjdy lsrSu


Gas Law ans -1

jdhq j, yeisrsus
1 iq<x msrjQ ne,qhl WIaK;ajh  wkqj fjkia jkafka  ljr .=Kdx.h o@
ialkaOh
mrsudj
msvkh
>k;ajh
mrsudj  msvkh  >k;ajh
2  msiagkhla iys; isrskachl mqrjd we;s jdhqjl WIaK;ajh  wkqj fjkia jkafka  ljr .=Kdx.h o@

msvkh
>k;ajh
 3 isriaj msiagkh my<g fhduq jQ jdhqjla iys; isrskachl mrsudj fjkia lsrsug l=ula l< hq;= o@
mrsudj wvq lsrsug msiagkhla  by<g ;,a,q lsr’u
mrsudj jevs lsrsug msiagkhla  my<g weoSu
4 mrsudj jevs lsrsug msiagkhla  my<g weoSfus oS  jdhq wxY= w;r oqrg l=u;a isoqfjs o@
jdhq wxY= w;r oqrg wvq fjhs’
5 tu .=Kh ljr kulska y|qkajhs o@
iusmSvk yelshdj
6 o%jhlg idfmalaIj jdhqjl iusmSvk yelshdj flfia fjkia fjhs o@
by< w.hla .kshs’
7  iusu; WIaK;ajfha  yd mSvkh f,i i,lkafka  ljr ;;ajhka o@
fi'0 iy msvkh riosh fikags uSg¾ 76 $ jdhq f.da, 1$1·10 5 Pa
 8 jdhq fu!,hla wvx.= jkafka ljr mrsudjla ;=, o@ tys mj;sk wKq .Kk lSh o@
22400ml
9 ta i|yd Ndjs; lrk kshuh ,shkak
wej.vsfrda kshuh
10 fndhs,a kshuh f.dv ke.Sug  ljr ;;aj wjYH fjhs o@
ia:sr jdhq ialkaOhla
ksh; WIaK;ajhla
11 l=uk w.hhka fjkia l< hqq;= o@ ljr uskqus ,nd.; hq;= fjhs o@
msvkh
mrsudj
12 msvkh yd mrsudfjs .=Ks;h ms<sn| ljr wkdjels mejish yels o@
ksh;hla fjs’
13 tu jdhq ialkaOh fhdod .ksuska pd,aia kshuh  mrSlaId lsrSug l=uk w.hhka fjkia l< hqq;= o@
WIaK;ajh
14 ksh;j mj;ajd .; hq;= w.h ,shkak
msvkh
15 fuu kshu fol  tkus fndhs,a kshuh yd pd,aia kshu Ndjs; lr ,nd .kakd kshuh ,shkak tu kshuh imqrd,k iuSlrKh ,shkak
PV  ∞ T

ixhqla; jdhq kshuh
16 fndhs,a kshuh yd pd,aia kshu  yd wej.vsfrda kshuh Ndjs; lr ,nd .kakd kshuh ,shkak tu kshuh imqrd,k iuSlrKh ,shkak
PV  =nRT
mrsmQ¾K jdhq kshuh
17 fuys R f,i y|qkajkafka ljrla o@ th y|qkajk ku ,shkak
jdhq fu!,hlg wod, ksh;h
id¾j;% jdhq ksh;h
18 ljr ;;aj hgf;a ;d;ajsl jdhq fuu kshuh ms<smoshs o@ ta ljr ;;aj hgf;a o@
wvq wka;¾ wKql n, iys; jdhq  jsu
wvq msvkh iys; ;;aj we;sjsg
jdhqfjs ;dmdxlhg idfmalaIj b;d by< WIaK;aj we;sjsg
19 tjeks wm.ukhkag fya;= jQ lreKq ,shkak
jdhq wKqj, mrsudj fkdi,ld yersu ksid
wka;¾ wKql wdl¾IK n,  fkdi,ld  ksid

20 l=uk w.hhkaf.a fodaI we;s lsrSug th iu;a fjhs o@
jdhq wKqj, mrsudj fkdi,ld yersu ksid mrsudfjs fodaI we;sjSu
wka;¾ wKql wdl¾IK n,  fkdi,ld  ksid mSvkfha fodaI we;sjSu
21 ;d;ajsl jdhq  j,g .e,fmk f,i fuu kshuh bosrsm;a lf<a  ljqo@
jekavjd,a jsiska
22 ljr fYdaOkhka ta i|yd bosrsm;a lr ;sfns o@
jdhq wKqj, mrsudj i|yd fYdaOkhla fhosu $ n b w.h wvq lsrSu
23 mSvkh i|yd fYdaOkhla fhoSug isoqjQfha wehs@
jdhq wKq w;r wdl¾IKh ksid mrsmQ¾K jdhqjg  jvd ;d;ajsl jdhq j, mSvkh wvq fjhs’


24 jdhq wKq w;r wdl¾IKh ksid we;sjk n,h tall mrsudjl we;s jdhq wKq .Kkg $ >k;ajhg iudkqmd;sl fjhs tysoS fhdok fYdaOk w.h ,shkak
n2 a / V2
25 mSvkh i|yd fYdaOk w.h tl;= l< hq;= o@ wvq l< hq;= o@

fYdaOk w.h tl;= l< hq;= h

Chemistry Kinetics ans -3

pd,l ridhkh 3
1 m%;sls%hl idkao%Kh jevs l< jsg M, ieoSfus fjs.h jevsfjhs’’ thg fya;=j l=ula o@
M, ieoSu i|yd m%;sls%hl wKq fyda whk w;r .egsus we;sjsh hq;=h fuysoS m%;sls%hl wKq w;r .egSus ixLHdj jevs jSu M, iEoSug we;s wjia:dj jevss lrhs
2 .egSu fya;= fldg f.k wKqjl ljr fjkila we;s fjhs o@
tys pd,l Yla;sh fjkia fjhs
3 w|qr we;sjsg  ldur WIaK;ajfha oS yhsv%cka yd laf,darSka w;r m%;sls% hdj isoq fkdfjhs   wKql .egSu wkqj th meyeos,s lrkak
m%;sls%hl wKq w;r .egSus ixLHdj jevs jSfuka muKla fuu M, iEoSu isoqjsh fkdyel
4 r;a l< jsg fuu m%;sls%hdj isoq jkafka wehs
;dm Yla;sh ksid wKq j, pd,l Yla;sh jevsjsu .egSus ixLHdj jevs lsrSug fya;= fjhs
animescience.webatu.com  j, we;s  tka;e,ams jSvsfhdaaaj krUkak
H2  ,  InkaOk Yla;s ms<sfj,ska 436 KJ  151 KJ fjs kus
H2 + I2 ------ 2HI  m%;sls%hd ;dmh

5    H2 yd I2 nkaOk ns|Su i|yd jehjk uq¿ Yla;s m%udKh lSh o@
     587 KJ
6 tfy;a fuu m%;sls%hdj wdrusN lsrSug msg;ska iemhSug wjYH jkafka 165 KJ m%udKhls
   fuu Yla;s m%udKh ljr kulska ye|skafjhs o@ th wjYH jkafka l=ulg o@
       il%shk Yla;sh
7 il%shk Yla;sh w.h fjkia l< yelafla l=ulg o@
      W;afm%arl j,g
     w;rueos ixls¾Kh iEoSugh
8 fjs.fhka isoqjk m%;sls%hdjl il%shk Yla;s w.h l=ula fjs o@
     il%shk Yla;sh wvq fjhs
9 iuyr m%;sls%hd mshjr lsysmhlska isoq fjhs tla tla mshjrl il%shk Yla;s w.h l=ula  fjs o@ tjekakla isoqjk ld,h ;SrKh lrkafka flfia o@
       mshjr wkqj il%shk Yla;s w.h fjkia fjhs il%shk Yla;s w.h jevs kus m%;sls%hd fjs.h wvqfjhs
il%shk Yla;s w.h jevs mshjr u; m%;sls%hdj isoqjk ld,h ;SrKh fjhs
10 m%;sls%hd fjs.h jevs mshjrg hus ix>glhla idkao%Kh n,meus we;s lrhs o@ tys  m%;sls%hd fm< w.h lsho@
ke;
Y+kHhs
11 Yla;sh imhd .kafka wKql ix>gkh u.sk ,nd .; yelsh tu.ska ,efnk Yla;sh m%udKj;a fjhs kus tjeks m%;sls%hdjl iajNdjh ,shkak
th ldur WIaK;ajfha oS isoqfjhs
12 tu.ska ,efnk Yla;sh m%udKj;a fkdfjhs kus tjeks m%;sls%hdjl iajNdjh ,shkak
m%;sls%hdjl ;dm wjfYdaIl fjhs
th ldur WIaK;ajfha oS isoq fkdfjhs
13 iuyr m%;sls%hd ;dm odhl jkafka wehs@
nkaOk iEoSfusoS msgjk Yla;sh  nkaOk nsoSfusoS wjfYdaIkh lrk Yla;shg jvd jevsjk jsg
14 mshjr lsysmhlska isoqjk jsoHd.drh ;=, ksrSlaIKh l< yels m%;sls%hd i|yd WodyrK fokak

15 m%;sls%hl idkao%Kh jevssl, jsg m%;sls%hd fjs.h jevs jkafka wehs@
.egqus ixLHdj jevsjk ksid h
16  m%;sls%hl idkao%Kh jevssl, jsg m%;sls%hd fjs.h jevs jSu iEu jsgu isoq= fjhs o@ ta i|yd iusmQ¾K jsh hq;= ;j;a wjYH;djla  ,shkak
kshus; osYdk;shla wkqj .egqus we;sjSu
ils%hk Yla;s lvbu blaujd  .sh wKq w;r  .egSus we;sjsuhq;=h
17 iM, ix>gkhla hkq l=ula o@
ils%hk Yla;s lvbu blaujd  .sh wKq w;r  kshus; isYdk;shla wkqj .egSus we;sjsu

18 WIaK;ajh jevs l< jsg m%;sls%hd fjs.h jevsjkafka wehs@
ils%hk Yla;s lvbu blaujd  .sh wKq w;r .egSus jevsjSu ksid
19 leg jYfhka .ekSug jvd l=vq jYfhka .ekSfusoS m%;sls%hd fjs.h jevsjkafka wehs@
l=vq jYfhka .ekSfusoS ld, tallhloS isoqjk .egqus ixLHdj jevsfjhs
my; oelafjk m%;sls%hd i|yd wjYH jk W;afm%arl fudkjdo@
20 wod, W;afm%al f;darkak
MnO2 /CuSO4 /NO/H2O  /Fe / Ni /V2O5
is.rgs w¿ $
m%;sls%hl                          M,
2SO2 (g ) + O2  ………….      2SO3  
H2  +  Cl2          ………..     2HCl
N2 + 3H2          ………..     2NH3
C2H4 +H2     ………       C2H6
H2O2   …….H2O + O2
KClO3 ……. KCl + O2
Zn +HCl …… Zn Cl2 +H2
21 iucd;Sh W;afm%arl hkq fudkjd o@ iucd;Sh W;afm%arl f;darkak
W;afm%arl yd m%;sls%hl tlu l,dmfha msysgk jsg
NO/H2
22 jsIucd;Sh W;afm%arl hkq fudkjd o@ iucd;Sh W;afm%arl f;darkak
W;afm%arl yd m%;sls%hl fjkia l,dmfha msysgk jsg
23 wOsfYdaIK ls%hdj,sh jeo.;a jkafka l=uk W;afm%arl i|yd o@
jsIucd;Sh W;afm%arl
24 wOsfYdaIK ls%hdj,sh ;=, isoq jkafka l=ula o@
W;afm%arl mDIaGh iu. m%;sls%hl wKq nkaOk iEoSu
25 tys m%;sM,h jkafka l=ula i@
m%;sls%hl wKq w;r nkaOk oqn, jSu
m%;sls%hl wKq kshus; osYdk;shlg wkqj fhduq lsrSu
26 W;afma%rlhlg  isoql< yels ld¾hh$ ld¾hhka f;darkak
m%;sls%hd iS>%;dj  wvqfjs jevsfjs fjkiafjs
m%;sls%hdjla wjidkfha W;afma%rlhl  m%udKh   fjkiafjs   fjkiafkdfjs
W;afma%rlhla  m%;sls%hdjlg iyNd.sfjs $ iyNd.s fkdfjs
W;afma%rlhla  u.ska m%;sls%hdj iu;=,s;;d ,laIh fjkia lrhs $ fjkia fkdlrhs
bosrs yd miq m%;sls%hd foflysu iS>%;dj  wvqlrhs$ jevslrhs
W;afma%rlhla  m%;sls%hdjl tka;e,amsa w.h fjkia lrhs $ fjkia fkdlrhs
W;afma%rlhl ls%hdj fjk;a o%jH u.ska j¾Okh fjs $ j¾Okh fkdfjs





Chemistry Kinetics ans -2

pd,l ridhkh -2


Na2S2O3 + HCl ------NaCl +SO2 +S +H2O
fuu m%;sls%hdfjs fm< fijSug wjYHj we;ehs is;kak

R ۓ [S2O3--]m
1 1 m w.h fijSug mrslaIK ie,iqus lrk wjYH o%jH fudkjdo@
3M HCl yd 0'1M Na2S2O3 - nslrh jsrdu >gSldj- l;srh w\sk ,o lvodish

2   2 m w.h fijSug mrslaIK ie,iqus lrk jsg l=ul idkao%Kh fjkia l< hq;= o@

0'1M Na2S2O3 o%djKh
3 fuu mrSlaIKfhaoS ksh;j mj;ajd .; hq;= wfk;=;a idOl ,shkak
ksh; M, m%udKhla iEoSug .;jk ld,h ueksu fuysoS isoq lrhs ljr M,hla fuysos ukskq ,nhs o@
ksh; S m%udKhla iEoSug .;jk ld,h ueksu

4 ksh; S m%udKhla iEoSu y|qkd .kafka flfia o@
l;srh fkdfmkS hdug ieosug wjYH S m%udKh iEu jsgu ksh; f,i ie,lhs



k, wxlh 1 2 3 4 5

HCl wus,fha mrsudj 5 ml 5 ml 5ml 5 ml 5 ml

tl;= l< 0'1M Na2S2O3 mrsudj 25 ml 20 ml 15ml 10ml 5ml


5 msgjk H2 mrsudj tl;= wruqK l=ula o@ tf,i ueksug wjYH fjk;a idOlhla ,shkak
ksh; M, m%udKhla ,nd .ekSu $ ksmojSu
ld,h

6 m%;sls%hd iS>%;dj fidhkafka flfia o@
m%;sls%hd iS>%;dj iEoqKq S m%udKh$ ld,h

7 Na2S2O3 idkao%Kh fjkia lrkafka flfiao
kshus; Na2S2O3 mrsudj fhdod mrSlaIK k,h msfrk ;=re c,h fhoSu

8 k, wxl 5 idfmalaIj k, wxl 4 idkao%Kh lS .=Khla fjhs o@
fo.=khla

9 k, wxl 5 idfmalaIj k, wxl 3 idkao%Kh lS .=Khla fjhs o@
;=ka .=khla







k, wxlh                       1    2    3    4     5

HCl wus,fha mrsudj           5 ml 5 ml 5ml 5 ml 5 ml

tl;= 0'1M Na2S2O3 mrsudj  25 ml 20 ml 15ml 10ml 5ml

l;srh fkdfmks hdug 18 20 24 38 80
.;jk ld,h ;;a'

10 m%;sls%hd iS>%;dj yd S m%udKh tl;=jsu i|yd .;jQ ld,h w;r iusnkaO;dj l=ula o@
R 1/t

m%;sls%hd iS>%;dj ^R )S m%udKh tl;=jsu i|yd .;jQ ld,hg ^t& m%;sf,dauj iudkqmd;sl fjhs

11 wus, idkao%Kh;a wus, mrsudj;a w;r iusnkaO;djh l=ula o@

wus, idkao%Kh;a wus, mrsudj g ^V& wkqf,dauj iudkqmd;sl fjhs

12 ta wkqj fuu iuslrKh ilikak

R ۓ [S2O3--]m

1/t ۓ [V]m
13 m=1 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka
14 m=2 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V 2 w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka

15 m=3 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V3 w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka
16 fus m w.h fidhd .eksug ,>q w.h Ndjs; l< yelafla flfia o@
,>q t yd ,>q V w;r m%ia;drhla we|Su yd wkql%ukh fijsu wkql%ukh = m w.h


17 j.+fjs i|yka ld,h wkqj fm< .Kkh lrkak









Chemistry Kinetics ans -1


1 BaCl2 o%djKhlg i,afmag nsxoq lsysmhla
tl;= l< jsg laIkslj fjkiajSula we;s fjhs tu fjki l=ula o@
iqoq wjlafIamhlaa ,ensu

2 C2O4 o%djKhlg ;kql H2SO4 j,ska wdus,sl fldg KMnO4 fhoQ jsg fjkia jSula we;sjsug .;jk ld,h jevs fjhs we;s jk tu fjki l=ula o@
දමි meyeh wj¾K jSu

3 tjeks ld, fjkiajSula i|yd fya;= ,shkak

fojk m%;sls%hdfjs fjs.h wvqjSu

4 .%Eus 5 l hlv weKhlg jvd fjs.fhka hlv l=vq .%Eus 5 la iu. ;kql 0'2 M H2SO4 wus,h
5 ml iu. nqnq,q we;s lrhs
5 m%;sls%hdfjs fjs.h fjkiajSu flfrys we;s jQ n,mEu l=ula o@ thg fya;= ,shkak'

fN!;sl ;;ajh
>k ;;ajhloSg jvd l=vq f,i mej;sfus oS wus, iu. .efgk m!IaGh jevs jSu

6 KMnO4 5 ml ^;kql H2SO4 j,ska wdus,sl l<& wvx.= k, follg fjk fjku f.k thg hlv l=vq .%Eus 2 la fjk fjku tl;= lsrSu tla k,hla r;a lr wfkla k,h ldur WIaK;ajfha ;enSu

7 ljr jsm¾hdihla n,dfmdfrd;a;= jkafka o@ thg fya;= ,shkak'
r;a l< k,fha ous meyeh blaukska oqUqre meyeh we;sfjhs
oqUqre meyeh we;s jQfha wehs @
Fe+++ we;s jSu

8 m%;sls%hdfjs fjs.h fjkiajSu flfrys we;s jQ n,mEu l=ula o@
WIaK;ajh

9 0'002 M Na2S2O3 o%djKhl 5 ml lg 0'2 M ;kql wus,h 2 ml fhoQ jsg we;sjk ksrSlaIK ,shkak
bka miq 0'001 M Na2S2O3 o%djKhl 5 ml lg 0'2 M ;kql wus,h 2 ml fhoQ jsg we;sjk ksrSlaIK ,shkak
o%djKfha wmeyeos,s njla we;sjSu'
fojk wjia:dfjs oS ta i|yd .;jk ld,h jevsh'

10 m%;sls%hdfjs fjs.h fjkiajSu flfrys we;s jQ n,mEu l=ula o@
Na2S2O3 o%djKhl idkao%Kh fjkia jSu

11 iskala f,dayh .%Eus 5 la iu. ;kql 0'2 M HCl wus,h 5 ml lg ^CusO4 nsxoq lsysmhla fhoQ &iu.o iskala f,dayh .%Eus 5 la iu. ;kql 0'2 M HCl wus,h 5 ml iu. o tl jsg m%;sls%hd lrjQ jsg jvd;a blaukska f,dayh oshjkafka m<uq k,fhah' thg fya;=j l=ula o@
fldm¾ whk W;afm%arl f,i ls%hd lsrSu ksid


12 H 2 yd Cl2 w;r m%;sl%shdj ldur WIaK;ajfhaoSg jvd fjs.fhka wdf,dalfhaoS m%;sls%hd fjhs
iEfok M,h l=ula o@
13 ta i|yd mrslaIK ie,iqus lsrsfusoS wjYH ridhksl o%jH ,shkak
HCl $>k KMnO4 $ Zn

14 jdhq tla reia lrkafka ljr l%uhg o@
c,h hgsl=re jsia:dmk l%ufhka

15 c,h ;=,oS jdhq usY% l< miq M,h iEfok nj Tn y|qkd.kafka flfia o@
c, ugsgu by< ke.Su u.ska
s
16 m%;sls%hdj jevs fjs.hlska isoqjk nj fidhd .kafka flfia o@
wvq ld,hla ;=, c, ugsgu by< k.shs

17 ridhksl m%;sls%hdjl iS>%;dj flfrys n,mdk idOl fudkjd o@
fN!;sl ;;ajh $ W;afm%arl $m%;sls%hl idkao%Kh$wdf,dalh$WIaK;ajh


18 >k le,aishus ldnfkags .Eus 10 la iu. 2 M HCl 50 ml tl;= lf<a hehs is;kak msgjk jdhqj nshqfrgsgqjlg tl;= lf<a hehs is;kak';;amr 30 lg jrla tl;=jQ jdhq mrsudj uek .;af;a kus ljr wdldrfha m%ia;drhla ,efnkq we;a o@


19 isoqjk m%;sls%hdj i|yd iuslrKhla ,shkak


20 m%;sls%hdfjs iS>%;dj fidhkafka flfia o@
m%;sls%hdfjs iS>%;dj tl;= jQ jdhq mrsudj $ld,h

21 m%;sls%hdfjs iS>%;djh flfia fjkiafjs hehs Tn n,dfmdfrd;a;= jkafka o@

tu w.h l%ufhka wvq jSu

22 ta i|yd fya;= bosrsm;a lrkak
wus,h jehjSu ksid tys idkao%Kh l%ufhka wvq jk ksid m%;sls%hd iS>%;dj o l%ufhka wvqfjhs

23 m%;sls%hdfjs iS>%;djh fijsug tu moaO;sh fhdod .kafka kus jvd;a iqoqiq jkafka ljr wjia:djo@
wdrusNl wjia:dfjsosh
24 m%;sls%hdfjs iS>%;djh fijsug jvd;a iqoqiq moaO;shla ilia lsrsfus oS by; fodaIh u. yrjd .; yels fjk;a l%uhla ,shkak
wdrusNl idkao%Kh by< w.hl mj;ajd .eksu

25 m%;sls%hdfjs iS>%;djh iEujsgu idkao%Khg wkqf,dauj iudkqmd;sl fjs fuu m%ldYh ksjeros lrkak

m%;sls%hdfjs iS>%;djh iEujsgu idkao%Kfha lsishus n,hlg wkqf,dauj iudkqmd;sl fjs
aA + bB ------ cC + dD
26 tu m%ldYh iuSlrKhlska fokak ^ oS we;s iuSlrKh i|yd &
1 R ۓ [A m] ۓ = iudkqmd;sl nj
11 R ۓ [A m] [B n]
27 m%;sls%hd fm< f,i y|qkajkafka l=ula o@
1 m

Mg + HCl ------MgCl2 +H2
28 fuu m%;sls%hdfjs fm< fijSug wjYHj we;ehs is;kak

R ۓ [HCl]m
29 m w.h fijSug mrslaIK ie,iqus lrk wjYH o%jH fudkjdo@
4cm ue.akSishus mgs- 1M HCl - rn¾ wen - jSoqre ng - jsrdu >gSldj- kQ,a lene,a,

30 m w.h fijSug mrslaIK ie,iqus lrk jsg l=ul idkao%Kh fjkia l< hq;= o@

HCl wus,fha
31 fuu mrSlaIKfhaoS ksh;j mj;ajd .; hq;= wfk;=;a idOl ,shkak
tl;= jk jdhq mrsudj

wus,h iu. .efgk Mg m%udKh

k, wxlh 1 2 3 4 5

HCl wus,fha mrsudj 10 ml 8 ml 6ml 4 ml 2 ml

tl;= jk jdhq mrsudj

32 msgjk H2 mrsudj tl;= wruqK l=ula o@ tf,i ueksug wjYH fjk;a idOlhla ,shkak
ksh; M, m%udKhla ,nd .ekSu $ ksmojSu
ld,h

33 m%;sls%hd iS>%;dj fidhlafka flfia o@
m%;sls%hd iS>%;dj iEoqKq jdhqfjs mrsudj$ ld,h

34 wus, idkao%Kh fjkia lrkafka flfiao
kshus; wus, mrsudj fhdod mrSlaIK k,h msfrk ;=re c,h fhoSu

35 k, wxl 5 idfmalaIj k, wxl 4 idkao%Kh lS .=Khla fjhs o@
fo.=khla

36 k, wxl 5 idfmalaIj k, wxl 3 idkao%Kh lS .=Khla fjhs o@
;=ka .=khla

k, wxlh             1      2     3    4     5

HCl wus,fha mrsudj 10 ml 8 ml 6ml 4 ml 2 ml

H2 mrsudj 10 ml tl;=jsu
i|yd .;jQ ld,h


37 m%;sls%hd iS>%;dj yd H2 mrsudj 10 ml tl;=jsu i|yd .;jQ ld,h w;r iusnkaO;dj l=ula o@

m%;sls%hd iS>%;dj ^R ) H2 mrsudj 10 ml tl;=jsu i|yd .;jQ ld,h g^t& m%;sf,dauj iudkqmd;sl fjhs R 1/t

38 wus, idkao%Kh;a wus, mrsudj;a w;r iusnkaO;djh l=ula o@

wus, idkao%Kh;a wus, mrsudj g ^V& wkqf,dauj iudkqmd;sl fjhs

39 ta wkqj fuu iuslrKh ilikak

R ۓ [HCl]m

1/t ۓ [V]m
40 m=1 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka
41  m=2 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V 2 w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka

42  m=3 fjhs o hkak y|qkd .kafka flfia o@
1/t yd V3 w;r m%ia;drhla we\Sfuka uQ, ,laIh yryd hk ir, f¾Ldjla ,efns o hkak ne,sfuka
43 fus m w.h fidhd .eksug ,>q w.h Ndjs; l< yelafla flfia o@
,>q t yd ,>q V w;r m%ia;drhla we|Su yd wkql%ukh fijsu wkql%ukh = m w.h